Orderly power utilization is an important means of power demand side management to ease the tension between power supply and demand during peak power consumption. Rotation is one of the important measures for orderly power utilization. Transferring users’power load to the low power consumption period can not reduce users’power consumption. When formulating the traditional orderly power utilization rotation scheme, extensive measures such as one size fits all rotation according to the power load and power rationing are generally adopted, ignoring the impact of some enterprises’rotation on the coordinated operation of the industrial chain. To this end, a strategy for formulating an orderly electricity rotation scheme considering the industrial chain is designed. Users in the same industrial chain are aggregated into a user instance to jointly participate in the preparation of the rotation scheme. Users participating in the orderly electricity rotation are selected according to the rotation value index, and the rotation grouping is optimized to minimize the peak load of the rotation, so as to reduce the impact of the rotation on normal production and life. The results show that the above scheme can enable users in the same industrial chain to implement the same rotation strategy, and reduce the impact of partial rotation on production and operation of users in the industrial chain. It is more fair and reasonable to determine the users participating in the rotation according to the rotation value index.